Syn regioselectivity of the hydroperoxidation of cyclo-alkenes with singlet oxygen
โ Scribed by Charles W. Jefford; Christian G. Rimbault
- Publisher
- Elsevier Science
- Year
- 1981
- Tongue
- French
- Weight
- 221 KB
- Volume
- 22
- Category
- Article
- ISSN
- 0040-4039
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๐ SIMILAR VOLUMES
The reaction of singlet oxygen with cis olefins is regioselective and shows a general preference for hydrogen abstraction on the larger alkyl group of the double bond.
Generation and Reactivity of Singlet Oxygen within Zeolites: Remarkable Control of Hydroperoxidation of Alkenes. -The alkenes (I), (IV), (VII), and (X) included within a Y zeolite are selectively oxidized by singlet oxygen generated via excitation of a monomeric dye exchanged within a zeolite. The
## Abstract The regioselectivity of the hydroperoxidation of tetrasubstituted olefins by singlet oxygen is rationalized in terms of the zwitterionic peroxide model.