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The reaction of singlet oxygen with a simple thiophene

✍ Scribed by C.N. Skold; R.H. Schlessinger

Publisher
Elsevier Science
Year
1970
Tongue
French
Weight
174 KB
Volume
11
Category
Article
ISSN
0040-4039

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✦ Synopsis

Current interest in the reactions of singlet oxygen with heterocyclic systems prompts us to describe some of our own efforts in this area.' The marked reactivity of singlet oxygen with cis-dienes is well documented,' and this behavior suggested that it might be possible to obtain a reaction between singlet oxygen and simple thiophenes.

This supposition has proven correct for we have found that photogenerated singlet oxygen undergoes an interesting and facile reaction with 2,5_dimethylthiophene (1j.s Irradiation (4 hrs) of chloroform solutions of l(O.013 M) with 520 nm light absorbed only

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