## Abstract For Abstract see ChemInform Abstract in Full Text.
Reactions of organolithium reagents with amines; syntheses of ketones and α-substituted amines from primary amines
✍ Scribed by Herman G. Richey Jr.; Wayne F. Erickson; Alan S. Heyn
- Publisher
- Elsevier Science
- Year
- 1971
- Tongue
- French
- Weight
- 203 KB
- Volume
- 12
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
✦ Synopsis
Reactions under mild conditions of primary amines with an excess of an organolithium reagent furnish (after hydrolysis) unexpected products: a-substituted amines and ketones.
📜 SIMILAR VOLUMES
reoeiwd ia UK for pnblioatioa 5 Jnns 1972) We have isolated imines as significant products from reactions of primary amines with organolithium reagents in excess. This work provides both a new way
The first syntheses of (~0t'-diperfluofoalkylated)diamines are reprgted together with a range of substituted ¢t-perflucfoalkylated amines all prepared in good yields from benzotriazole derivatives and perfluoroalkyl Grignard reagents in the presence of BF3.Et~O. Primary amines are conveniently obtai