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Syntheses of perfluoroalkylated amines and diamines by reactions of perfluoroalkyl grignard reagents with N-(α-aminoalkyl)benzotriazoles

✍ Scribed by Alan R. Katritzky; Zhongxing Zhang; Ming Qi

Publisher
Elsevier Science
Year
1997
Tongue
French
Weight
172 KB
Volume
38
Category
Article
ISSN
0040-4039

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✦ Synopsis

The first syntheses of (~0t'-diperfluofoalkylated)diamines are reprgted together with a range of substituted ¢t-perflucfoalkylated amines all prepared in good yields from benzotriazole derivatives and perfluoroalkyl Grignard reagents in the presence of BF3.Et~O. Primary amines are conveniently obtained from Pd-catalyzed hydrogenations.

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