Reactions under mild conditions of primary amines with an excess of an organolithium reagent furnish (after hydrolysis) unexpected products: a-substituted amines and ketones.
Formation of imines in reactions of primary amines and lithium reagents
โ Scribed by Wayne F. Erickson; Herman G. Richey Jr.
- Publisher
- Elsevier Science
- Year
- 1972
- Tongue
- French
- Weight
- 153 KB
- Volume
- 13
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
โฆ Synopsis
reoeiwd ia UK for pnblioatioa 5 Jnns 1972)
We have isolated imines as significant products from reactions of primary amines with organolithium reagents in excess. This work provides both a new way
๐ SIMILAR VOLUMES
2,6-Diisopropyz .-substituted pyryliwn salts 5 react with primary wnines RNH, yielding pyridinium salts, g, and 6,6-dimethyl-2,4-eyclohesadi&yZidene-l-iminium salts, z, in relative cmwunts depending on the group R (160/O for R = Me, 4317 for R = Et, 20/80 for R = iPr, and O/G for R = tBul urovinq th
## Abstract For Abstract see ChemInform Abstract in Full Text.