Reactions of primary amines with epoxides
β Scribed by John F. Harrod
- Publisher
- John Wiley and Sons
- Year
- 1962
- Tongue
- English
- Weight
- 176 KB
- Volume
- 6
- Category
- Article
- ISSN
- 0021-8995
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π SIMILAR VOLUMES
## Synopsis Since oxidizability of raw rubber is adversely affected by epoxidation, an attempt was made to bind an amine antioxidant to the rubber molecule through the oxirane group. Effective binding was observed only if the latex is neutralized before addition of the amine. Of the three amines u
wR2 = 0.0866 (against I F 2 I ), Y scan. The data for 1 were collected on a STOE four-circle diffractometer at -70Β°C under a nitrogen atmosphere. The structure was solved by direct methods with the program SHELXS86 [lo] and was refined anisotropically with SHELXL93 [ll]. The H atoms of the water mol