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Reactions of (Me3SiCH2)2AsSiMe3 with gallium halides; crystal structure and dynamic NMR study of the dimer [[(Me3SiCH2)2As]2GaBr]2

✍ Scribed by Purdy, Andrew P.; Wells, Richard L.; McPhail, Andrew T.; Pitt, Colin G.


Book ID
126979397
Publisher
American Chemical Society
Year
1987
Tongue
English
Weight
968 KB
Volume
6
Category
Article
ISSN
0276-7333

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The dimeric gallium-phosphorus compound [(Me 3 Si-CH 2 ) 2 GaP(SiMe 3 ) 2 ] 2 (1) was prepared from the 1:1 mole ratio lithium-halide elimination reaction of (Me 3 SiCH 2 ) 2 GaP(SiMe 3 ) 2 Ga(CH 2 SiMe 3 ) 2 Cl with LiP-(SiMe 3 ) 2 in benzene solution and has been characterized through multinuclear