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Synthesis and characterization of gallium-arsenic compounds containing a four-membered GaAsGaCl or GaAsGaAs ring: crystal structures of (Me3SiCH2)2GaAs(SiMe3)2Ga(CH2SiMe3)2Cl and [(Me3SiCH2)2GaAs(SiMe3)2]2

✍ Scribed by Richard L. Wells; James W. Pasterczyk; Andrew T. McPhail; James D. Johansen; Abbas Alvanipour


Book ID
107811923
Publisher
Elsevier Science
Year
1991
Tongue
English
Weight
1003 KB
Volume
407
Category
Article
ISSN
0022-328X

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Preparation and characterization of arsi
✍ Ryan A. Baldwin; Hamid Rahbarnoohi; Leonidas J. Jones III; Andrew T. McPhail; Ri 📂 Article 📅 1996 🏛 John Wiley and Sons 🌐 English ⚖ 680 KB

As(SirBuMe,), (1) was prepared by the salt-elimination reaction between (Na/K), As and 'BuMe,SiCI. Mixing LiAs(SiMe,), with Ph,SiCl (1:l) yielded As(SiMe,),(SiPh,) (2) in a good crystalline yield. Reaction of 2 (1:I) with Et,Ga gave the expected Lewis acid-base adduct Et,Ga \* As(SiMe,),(SiPh,) (3).