The twist-boat conformation in a gallium-arsenic six-membered ring: crystal structure of [(Me3SiCH2)2AsGaBr2]3
✍ Scribed by Richard L. Wells; Andrew P. Purdy; Andrew T. McPhail; Colin G. Pitt
- Publisher
- Elsevier Science
- Year
- 1988
- Tongue
- English
- Weight
- 360 KB
- Volume
- 354
- Category
- Article
- ISSN
- 0022-328X
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## Abstract The crystal and molecular structure of the benzo‐fused seven‐membered‐ring phosphorus heterocycle, 2‐phenyl‐2‐oxo‐5,6‐benzo‐1,3,2‐dioxaphosphepane, has been determined by single‐crystal X‐ray techniques. The compound crystallizes in the monoclinic space group __P__2~1~/c with four molec
X-ray crystallographic analyses are reported for the two title compounds (8 and 9), of which the former crystallized in two modifications (8n and 8b). In all three structures, the pyranose rings have the %, (D) conformation and the substituents at C-l are axial and those at C-24-4 are equatorial. Th