✦ LIBER ✦
Synthesis and characterization of [(Me3SiCH2)2GaP(SiMe3)2]2, an example of a gallium-phosphorus dimer obtainable only through an indirect reaction pathway
✍ Scribed by Richard L. Wells; Edward E. Foos; Ryan A. Baldwin; Arnold L. Rheingold; Glenn P. A. Yap
- Publisher
- John Wiley and Sons
- Year
- 1998
- Tongue
- English
- Weight
- 160 KB
- Volume
- 9
- Category
- Article
- ISSN
- 1042-7163
No coin nor oath required. For personal study only.
✦ Synopsis
The dimeric gallium-phosphorus compound [(Me 3 Si-CH 2 ) 2 GaP(SiMe 3 ) 2 ] 2 (1) was prepared from the 1:1 mole ratio lithium-halide elimination reaction of (Me 3 SiCH 2 ) 2 GaP(SiMe 3 ) 2 Ga(CH 2 SiMe 3 ) 2 Cl with LiP-(SiMe 3 ) 2 in benzene solution and has been characterized through multinuclear solution NMR, partial elemental analysis, and single-crystal X-ray analysis. Compound 1 could not be obtained from the direct reactions of (Me 3 SiCH 2 ) 2 GaCl with P(SiMe 3 ) 3 or LiP(SiMe 3 ) 2 .