Reactions of isoprenoids. VII. Acid-catalyzed hydrolysis of1-(5,5-dimethylbicyclo[2.1.1]hexan-1-yl)-1,2-epoxyethane
β Scribed by Sasaki, Tadashi.; Eguchi, Shoji.; Ishii, Teruhiko.
- Book ID
- 127279445
- Publisher
- American Chemical Society
- Year
- 1970
- Tongue
- English
- Weight
- 450 KB
- Volume
- 35
- Category
- Article
- ISSN
- 0022-3263
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π SIMILAR VOLUMES
Despite their structural similarity to the carbon analogues, strained sulfur-bridged polycyclics have been much less studied. And except episulfide, the smallest member of the sulfur-bridged bicyclics ever reported was 2-or 7-thiabicyclo[2.2.1]heptane.
cis isomers of 2-catecholboryl-1-pinacolboryl-and bis(1,2pinacolboryl)-1,2-bis[4-(trifluoromethyl)phenyl]ethene substitute one another isomorphously in a 1:1 ratio. The molecule has no crystallographic symmetry, with one olefinic site shared equally between superimposed pinacol-and catecholboryls, a