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Solid solution of cis-1,2-bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-1,2-bis[4-(trifluoromethyl)phenyl]ethene–cis-2-(1,3,2-benzodioxaborolan-2-yl)-1-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-1,2-bis[4-(trifluoromethyl)phenyl]ethene–hexane solvate (1/1/1)

✍ Scribed by Bramham, George ;Batsanov, Andrei S. ;Marder, Todd B. ;Norman, Nicholas C.

Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
277 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis

cis isomers of 2-catecholboryl-1-pinacolboryl-and bis(1,2pinacolboryl)-1,2-bis[4-(trifluoromethyl)phenyl]ethene substitute one another isomorphously in a 1:1 ratio. The molecule has no crystallographic symmetry, with one olefinic site shared equally between superimposed pinacol-and catecholboryls, and the other occupied solely by a (disordered) pinacolboryl. CF 3 groups and hexane solvent molecules are also disordered.

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