## A brief synthesis of endo-2-bromo-5-thiabicyclo [2.1 .I]hexane (9) has been developed involving conversion of 3-cyclopentenol (6) to 3-thioacetoxycyclopentene (7), bromination of this giving trans-l,2-di- bromo-4-thioacetoxycyclopentane (8), and treatment of the latter with base. Compound 9 is
โฆ LIBER โฆ
Synthesis of 5-thiabicyclo[2.1.1]hexane
โ Scribed by Iwao Tabushi; Yoshinao Tamaru; Zen-ichi Yoshida
- Publisher
- Elsevier Science
- Year
- 1970
- Tongue
- French
- Weight
- 143 KB
- Volume
- 11
- Category
- Article
- ISSN
- 0040-4039
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โฆ Synopsis
Despite their structural similarity to the carbon analogues, strained sulfur-bridged polycyclics have been much less studied. And except episulfide, the smallest member of the sulfur-bridged bicyclics ever reported was 2-or 7-thiabicyclo[2.2.1]heptane.
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