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Synthesis of 5-thiabicyclo[2.1.1]hexane

โœ Scribed by Iwao Tabushi; Yoshinao Tamaru; Zen-ichi Yoshida


Publisher
Elsevier Science
Year
1970
Tongue
French
Weight
143 KB
Volume
11
Category
Article
ISSN
0040-4039

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โœฆ Synopsis


Despite their structural similarity to the carbon analogues, strained sulfur-bridged polycyclics have been much less studied. And except episulfide, the smallest member of the sulfur-bridged bicyclics ever reported was 2-or 7-thiabicyclo[2.2.1]heptane.


๐Ÿ“œ SIMILAR VOLUMES


Simple synthesis of endo-2-bromo-5-thiab
โœ Eric Block; Sriram Naganathan ๐Ÿ“‚ Article ๐Ÿ“… 1993 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 379 KB

## A brief synthesis of endo-2-bromo-5-thiabicyclo [2.1 .I]hexane (9) has been developed involving conversion of 3-cyclopentenol (6) to 3-thioacetoxycyclopentene (7), bromination of this giving trans-l,2-di- bromo-4-thioacetoxycyclopentane (8), and treatment of the latter with base. Compound 9 is

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