Synthesis of Aza-, Oxa-, and Thiabicyclo[3.1.0]hexane Heterocycles from a Common Synthetic Intermediate.
✍ Scribed by Adam R. Renslo; Hongwu Gao; Priyadarshini Jaishankar; Revathy Venkatachalam; Mikhail F. Gordeev
- Publisher
- John Wiley and Sons
- Year
- 2005
- Weight
- 27 KB
- Volume
- 36
- Category
- Article
- ISSN
- 0931-7597
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## Abstract Carbonyl ylide‐like intermediates are involved in the 1,5‐electrocyclization of the bicyclo[3.2.0]heptenes 3a–c. The activation barriers analyzed by the time‐ and temperature‐dependence of the __exo__ ⇌ __endo__ isomerization of specifically deuterated derivatives or of the racemization
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