2-Oxabicyclo[2.1.1]hexan und 2-Oxabicyclo[2.1.1]hex-5-yl-Derivate
✍ Scribed by Kirmse, Wolfgang ;Mrotzeck, Ume
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 1988
- Tongue
- English
- Weight
- 458 KB
- Volume
- 121
- Category
- Article
- ISSN
- 0009-2940
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
Dedicated to Prof. Ch. Tamm on the occasion of his 60th birthday (12.4.83) ## Summary (-)-1-Camphanoyloxyacrylonitrile (= (-)-1 -cyanovinyl camphanate; 1) obtained from the commercially available ( -)-camphanoyl chloride and 2-0x0propiononitrile added to furan at 20" in the presence of CU(BF,)~.
## Abstract Oxymercuration of __cis__, __cis__‐1, 5‐cyclooctadiene (**1**), followed by treatment with potassium iodide and subsequent reaction with iodine, leads to six isomeric diiodides which represent the three possible stereoisomers **2**, **3**, and **4** of 2, 5‐diiodo‐9‐oxabicyclo[4.2.1]non
## Abstract Iodine cleavage of the [3.3.1]‐iodomercuri compound **4**, easily prepared from __cis__, __cis__‐cyclooctadiene‐(1,5) by oxymercuration of the monoepoxide **1** (→ **3**) followed by treatment with potassium iodide, leads to three isomeric iodides **6, 7**, and **8**, the [3.3.1]‐__exo_