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A Synthesis of 5,5-Dimethylbicyclo[2.1.1]hexane-1-carboxaldehyde 1

✍ Scribed by Ebisu, Kikuye; Batty, Leoniece B.; Higaki, Jane M.; Larson, H. O.

Book ID: 126836343
Publisher: American Chemical Society
Year: 1966
Tongue: English
Weight: 521 KB
Volume: 88
Category: Article
ISSN: 0002-7863
DOI: 10.1021/ja00961a026

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## A brief synthesis of endo-2-bromo-5-thiabicyclo [2.1 .I]hexane (9) has been developed involving conversion of 3-cyclopentenol (6) to 3-thioacetoxycyclopentene (7), bromination of this giving trans-l,2-di- bromo-4-thioacetoxycyclopentane (8), and treatment of the latter with base. Compound 9 is