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Reactions of formamidinium salts with organolithium reagents

โœ Scribed by Hobbs, Charles F.; Weingarten, Harold


Book ID
121231871
Publisher
American Chemical Society
Year
1971
Tongue
English
Weight
654 KB
Volume
36
Category
Article
ISSN
0022-3263

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Reactions of triarylphosphines with orga
โœ Yuzuru Uchida; Masaaki Kawai; Haruo Masauji; Shigeru Oae ๐Ÿ“‚ Article ๐Ÿ“… 1993 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 585 KB

Triarylphosphines bearing 2-pyridyl or 2-benzothiazyl groups react with organolithium reugents at -78ยฐC in THF to afford both coupling products and ligand exchanged triarylphosphines. The ligand coupling and ligand exchange are considered to take place via an intermediate formed by the nucleophilic