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Novel reactions of perfluoroalkylphenyl sulfides with organolithium reagents

โœ Scribed by S. Munavalli; A. Hassner; D.I. Rossman; S. Singh; D.K. Rohrbaugh; C.P. Ferguson

Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
529 KB
Volume
73
Category
Article
ISSN
0022-1139

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โœ Yuzuru Uchida; Masaaki Kawai; Haruo Masauji; Shigeru Oae ๐Ÿ“‚ Article ๐Ÿ“… 1993 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 585 KB

Triarylphosphines bearing 2-pyridyl or 2-benzothiazyl groups react with organolithium reugents at -78ยฐC in THF to afford both coupling products and ligand exchanged triarylphosphines. The ligand coupling and ligand exchange are considered to take place via an intermediate formed by the nucleophilic