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The Reaction of Porphyrins with Organolithium Reagents

โœ Scribed by Mathias O. Senge; Werner W. Kalisch; Ines Bischoff


Publisher
John Wiley and Sons
Year
2000
Tongue
English
Weight
603 KB
Volume
6
Category
Article
ISSN
0947-6539

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Reactions of triarylphosphines with orga
โœ Yuzuru Uchida; Masaaki Kawai; Haruo Masauji; Shigeru Oae ๐Ÿ“‚ Article ๐Ÿ“… 1993 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 585 KB

Triarylphosphines bearing 2-pyridyl or 2-benzothiazyl groups react with organolithium reugents at -78ยฐC in THF to afford both coupling products and ligand exchanged triarylphosphines. The ligand coupling and ligand exchange are considered to take place via an intermediate formed by the nucleophilic