Reaction of triphenylsulfonium salt with organolithium reagents
โ Scribed by Shigeru Oae; Hiroyuki Ishihara; Masakuni Yoshihara
- Publisher
- Springer US
- Year
- 1995
- Tongue
- English
- Weight
- 381 KB
- Volume
- 31
- Category
- Article
- ISSN
- 0009-3122
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
Triarylphosphines bearing 2-pyridyl or 2-benzothiazyl groups react with organolithium reugents at -78ยฐC in THF to afford both coupling products and ligand exchanged triarylphosphines. The ligand coupling and ligand exchange are considered to take place via an intermediate formed by the nucleophilic
The reaction of phosphinoselenoic chlorides 1 with various organolithium and magnesium reagents was studied. Sequential reaction of phosphinoselenoic chlorides 1 with organolithium and magnesium reagents and elemental selenium gave two types of products, phosphine selenides 2 and phosphinodiselenoic