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Selenophilic reaction of organolithium and magnesium reagents with phosphinoselenoic chlorides

✍ Scribed by Tsutomu Kimura; Toshiaki Murai; Noriko Mizuhata

Publisher
John Wiley and Sons
Year
2005
Tongue
English
Weight
170 KB
Volume
16
Category
Article
ISSN
1042-7163

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✦ Synopsis

The reaction of phosphinoselenoic chlorides 1 with various organolithium and magnesium reagents was studied. Sequential reaction of phosphinoselenoic chlorides 1 with organolithium and magnesium reagents and elemental selenium gave two types of products, phosphine selenides 2 and phosphinodiselenoic acid esters 3. The esters 3 appeared to be formed via the selenophilic reaction of organolithium and magnesium reagents with the chlorides 1. Molecular orbital calculations were carried out for model compounds H 2 P(E)Cl

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