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Reactions of Doubly Bridged Bis(cyclopentadienes) with Iron Pentacarbonyl

โœ Scribed by Wang, Baiquan; Zhu, Bolin; Zhang, Jianyong; Xu, Shansheng; Zhou, Xiuzhong; Weng, Linhong


Book ID
127367041
Publisher
American Chemical Society
Year
2003
Tongue
English
Weight
426 KB
Volume
22
Category
Article
ISSN
0276-7333

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Reaction of iron pentacarbonyl with sulf
โœ Howard Alper ๐Ÿ“‚ Article ๐Ÿ“… 1969 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 166 KB

This communication reports a simple, rapid and convenient means of converting sulfonyl chlorides I to thiolsulfonate esters II using a 1:l mixture of iron pentacarbonyl and boron trifluoride ether-ate in N,N-dimethylacetamide (DMAC) or tetramethylurea (TMU). A typical procedure follows. BFx.(C7H5)7