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Reactions of Acid Chlorides/Ketenes with 2-Substituted 4,5-Dihydro-4,4-dimethyl-1,3-thiazoles: Formation of Penam Derivatives

✍ Scribed by Shi, Junxing; Linden, Anthony; Heimgartner, Heinz

Book ID
120833694
Publisher
John Wiley and Sons
Year
2013
Tongue
German
Weight
348 KB
Volume
96
Category
Article
ISSN
0018-019X

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## Abstract Addition reactions of organometallic reagents with 4,4‐disubstituted 1,3‐thiazole‐5(4__H__)‐thiones were studied. Whereas the reactions with alkyllithium and alkyl __Grignard__ reagents occurred in the thiophilic manner, the carbophilic addition was observed with allyllithium and allyl