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Reactions of 2-Iodobutane with Iodine. Evidence for a Radical Reaction with Inversion of Carbon

✍ Scribed by Herrmann, Raymond A.; Noyes, Richard M.

Book ID
121226250
Publisher
American Chemical Society
Year
1956
Tongue
English
Weight
797 KB
Volume
78
Category
Article
ISSN
0002-7863

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Replacement of N 2 by CO in H 2 + 02 + N 2 mixtures undergoing slow reaction at 500Β°C causes a marked increase in the reaction rate and a decrease in the induction period, expressed as the time to half maximum rate. A detailed interpretation using a computer treatment gives k24/klo 1/2 = 0.42 Β± 0.03