Kinetics of Several Oxygenated Carbon-Centered Free Radical Reactions with NO 2
β Scribed by Rissanen, Matti P.; Arppe, Suula L.; Timonen, Raimo S.
- Book ID
- 120412211
- Publisher
- American Chemical Society
- Year
- 2013
- Tongue
- English
- Weight
- 451 KB
- Volume
- 117
- Category
- Article
- ISSN
- 1089-5639
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π SIMILAR VOLUMES
## Abstract The rate constants for the reactions of the DS radical with NO~2~ (reaction 1) and ClNO (reaction 2) have been measured using the dischargeβflow technique at 2 torr total pressure of helium. The DS radical was monitored by laserβinduced fluorescence. The reactions were found to have the
## Abstract A novel technique is described for forming groundβstate SO __X__^3^Ξ£^ο£Ώ^ radicals free of reactive impurities in a dischargeβflow system. Mass spectrometric detection of SO and ClO free radicals has been used to study the kinetics of the following reactions at 295 K: equation image