Kinetics of resonance stabilized CH3CCCH2 radical reactions with NO and NO2
β Scribed by Matti P. Rissanen; Khushhal Popli; Raimo S. Timonen
- Book ID
- 116387111
- Publisher
- Elsevier Science
- Year
- 2012
- Tongue
- English
- Weight
- 371 KB
- Volume
- 543
- Category
- Article
- ISSN
- 0009-2614
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π SIMILAR VOLUMES
The rate constant for the reaction CH302 + NO2 -(products) has been measured directly by flash photolysis and kinetic spectroscopy. At room temperature and a t total pressures between 53 and 580 Torr, k:, = (9.2 f 0.4) X lo8 liter/mole sec so that the rate of formation of the probable primary produc
The reactions of GeH 3 with 02, NO, and NO 2 were studied via time-resolved infrared diode laser absorption spectroscopy over the temperature range 232-468 K for 02 and NO, and 252-407 for NO 2. The measured rate constants (in cm 3 molecule -1 s -1) were kGert3+o2 = (10 -13"18+Β°"18) exp[(874 + 146)/
Alkyl and alkylperoxy radicals originating from dimethyl ether have been studied in the gas phase at 296 K. A pulse radiolysis-UV absorption technique was used. Absorption cross-sections were quantified over the wavelength range 220-350 nm. At 230 nm, O'cH3oclJ2 = (4.2 + 0.5)Γ 10 -18 cm 2 molecule-l