✦ LIBER ✦

Kinetics of GeH3 reactions with NO, NO2, and O2

✍ Scribed by Robert W. Quandt; John F. Hershberger

Publisher: Elsevier Science
Year: 1995
Tongue: English
Weight: 414 KB
Volume: 233
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(94)01510-3

No coin nor oath required. For personal study only.

✦ Synopsis

The reactions of GeH 3 with 02, NO, and NO 2 were studied via time-resolved infrared diode laser absorption spectroscopy over the temperature range 232-468 K for 02 and NO, and 252-407 for NO 2. The measured rate constants (in cm 3 molecule -1 s -1) were kGert3+o2 = (10 -13"18+°"18) exp[(874 + 146)/T], k~H3+N o = (10 -13"3±0A9) exp[(736 + 345)/T], and kC~H~+NOz = (10 -11"42 ± 0.16) exp[(276 + 122)/T]. These results are consistent with formation of a collision complex with little or no entrance channel barrier.

📜 SIMILAR VOLUMES

Reactions of NO3-naphthalene adducts wit

Reactions of NO3-naphthalene adducts with O2 and NO2

✍ Roger Atkinson; Ernesto C. Tuazon; Isabelle Bridier; Janet Arey 📂 Article 📅 1994 🏛 John Wiley and Sons 🌐 English ⚖ 563 KB

## Abstract The kinetics of the gas‐phase reaction of the NO~3~ radical with naphthalene have been investigated at 150 torr O~2~ + 590 torr N~2~ and 600 torr O~2~ + 140 torr N~2~ at 298 ± 2 K. Relative rate measurements were carried out in reacting NO~3~N~2~O~5~‐naphthalene‐propene‐O~2~N~2~ mixtu

Kinetics of reactions of NH with NO and

Kinetics of reactions of NH with NO and NO2

✍ J.A. Harrison; A.R. Whyte; L.F. Phillips 📂 Article 📅 1986 🏛 Elsevier Science 🌐 English ⚖ 501 KB

Ground-state NH radicals were generated by 248 mn KrF laser photolysis of NsH4 and their concentration monitored by laser-induced fluorescence at 336 mn, at total pressures near 1 Torr and temperatures between 269 and 377 K. He, Ar, Ns and NsO were used as carrier gases. Rate constants obtained at 3

Kinetics of the SiH3 + O2 and SiH3 + NO2

Kinetics of the SiH3 + O2 and SiH3 + NO2 reactions

✍ Robert W. Quandt; John F. Hershberger 📂 Article 📅 1993 🏛 Elsevier Science 🌐 English ⚖ 551 KB

Kinetics of the reaction of CH3O with NO

Kinetics of the reaction of CH3O with NO2

✍ J.A. McCaulley; S.M. Anderson; J.B. Jeffries; F. Kaufman 📂 Article 📅 1985 🏛 Elsevier Science 🌐 English ⚖ 638 KB

&te coefficients for the reaction of Cl-I,0 ~th NO 2 were measured over the temperature range 21-O-473 K and over tie pressure range 0 6-4 0 Torr using a flow reactor apparatus uqth laser-Induced fluorescence (LIF) detection of CH,O The results were fitted LO extract recombmatlon and &sproporuonauon

Kinetics of the reaction of CH3O2 with N

Kinetics of the reaction of CH3O2 with NO

✍ I.C. Plumb; K.R. Ryan; J.R. Steven; M.F.R. Mulcahy 📂 Article 📅 1979 🏛 Elsevier Science 🌐 English ⚖ 346 KB

Kinetics of the reaction of CF3O2 with N

Kinetics of the reaction of CF3O2 with NO

✍ I.C. Plumb; K.R. Ryan 📂 Article 📅 1982 🏛 Elsevier Science 🌐 English ⚖ 201 KB

The rare cocificwn ior the rcact~on oiCF,02 with NO has been mcasurcd at 295 R m hcbum usins 3 ilow tube nmplcd by 2 rnxs spcctromurcr The KIIUC obrlmed ior this raw coeiircicnt was (17 8 f 3 6) x IO-'\* crK3 s-t and iound to bc indcpcndcnr of [Hc] over the range (6 3-16 8) x lOI cmm3. Tbls value is