Laser-excited fluorescence detection of HSiCl was used to measure the room-temperature kinetics of the reactions of HSiCl with SiH, and Sic&HZ. An upper bound was also obtained for the HSiCl+Hz rate coefficient. Rate coefftcients for insertion of HSiCl into SiH., and SiC12H2 are 3-4 orders of magnit
Kinetics of the SiH3 + O2 and SiH3 + NO2 reactions
β Scribed by Robert W. Quandt; John F. Hershberger
- Publisher
- Elsevier Science
- Year
- 1993
- Tongue
- English
- Weight
- 551 KB
- Volume
- 206
- Category
- Article
- ISSN
- 0009-2614
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π SIMILAR VOLUMES
## Abstract The multipleβchannel reactions SiH~3~ + SiH~3~CH~3~ β products and SiH~3~ + SiH~2~(CH~3~)~2~ β products are investigated by direct dynamics method. The minimum energy path (MEP) is calculated at the MP2/6β31+G(d,p) level, and energetic information is further refined by the MCβQCISD meth
## Abstract Disilylmethane is available in a fourβstep synthesis starting with phenylsilane. This is converted into chlorophenylsilane by HCl/AlCl~3~. The reaction of PhSiH~2~Cl and dibromomethane with magnesium in tetrahydrofuran affords bis(phenylsilyl)βmethane, which yields bis(bromosilyl)methan
I3he molecuIar structures of SiI-&N3 and (Sti3)2NCN have been detern&d by electron diffraction: Sii-I~Ns has a non-lincti SiNs skeleton, and (S~HJ)~NCN is a carbodiimide with SiNCKSi probably linear. A new model is pro-p&d which rationaLises the observed geome!ry of a number of molecu&r pseudohalide