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Gas phase electron diffraction study of SiH3N3 and (SiH3)2 NCN

✍ Scribed by C. Glidewell; A.G. Robiette

Publisher: Elsevier Science
Year: 1974
Tongue: English
Weight: 457 KB
Volume: 28
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(74)80075-8

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✦ Synopsis

I3he molecuIar structures of SiI-&N3 and (Sti3)2NCN have been detern&d by electron diffraction: Sii-I~Ns has a non-lincti SiNs skeleton, and (S~HJ)~NCN is a carbodiimide with SiNCKSi probably linear. A new model is pro-p&d which rationaLises the observed geome!ry of a number of molecu&r pseudohalides.

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