The insertion reactions of the titanium atom cation Ti F into HF, HCl, H O, H S, NH , PH , CH , and SiH have been studied by ab initio molecular orbital 2 2 3 3 4 4 theory. All these reactions involve the initial formation of an intermediate complex followed by a hydrogen migration process via a tr
Gas-Phase Protonation and Deprotonation of Acrylonitrile Derivatives NCCHCHX (X=CH3, NH2, PH2, SiH3)
✍ Scribed by Alberto Luna; Otilia Mó; Manuel Yáñez; Jean-François Gal; P.-C. Maria; Jean-Claude Guillemin
- Publisher
- John Wiley and Sons
- Year
- 2006
- Tongue
- English
- Weight
- 302 KB
- Volume
- 12
- Category
- Article
- ISSN
- 0947-6539
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The silanediols RN(SiMe3)Si(OSiMe3)(0H)2 (R = 2,4,6-were characterized by means of mass, IR and NMR (lH and Me3C6H2 4, 2,6-Me2C6H3 5 , and 2,6-iPr2C6H3 6) were prepa-2gSi) spectroscopy. Additionally, the molecular structures of red by the reactions of the respective silanetriols RN(SiMe3)-4 and 7 we