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The reaction of trifluoromethyl radicals with neopentane. An SH2 reaction at a saturated aliphatic carbon atom.

โœ Scribed by R.A. Jackson; M. Townson

Book ID
104246610
Publisher
Elsevier Science
Year
1973
Tongue
French
Weight
186 KB
Volume
14
Category
Article
ISSN
0040-4039

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Whereas reaction of trans-2-chloro or 2-bromo-3-tert-butyloxirane with thiophenc Zate occuรฏ>s at C-3 to gi7>e 2-phenylmercapto-3,3-dimethyZbutanaZ,phenoZates give substitution at C-2 witk retention of tke oxirane ring and retention of configuration witk kinetics tkat indicate a bimoZecuZar meckanism