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The reaction of OH radicals and HO2 radicals with carbon monoxide

✍ Scribed by G.M. Atri; R.R. Baldwin; D. Jackson; R.W. Walker

Publisher: Elsevier Science
Year: 1977
Tongue: English
Weight: 706 KB
Volume: 30
Category: Article
ISSN: 0010-2180
DOI: 10.1016/0010-2180(77)90046-3

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✦ Synopsis

Replacement of N 2 by CO in H 2 + 02 + N 2 mixtures undergoing slow reaction at 500°C causes a marked increase in the reaction rate and a decrease in the induction period, expressed as the time to half maximum rate. A detailed interpretation using a computer treatment gives k24/klo 1/2 = 0.42 ± 0.03 (litre tool -1 s--l) 112 from which k24 = 1.9 × 104 litre tool -1 s -1. Arrhenius parameters E24 = 96.0 kJ mo1-1, A = 5.8 × 1010 litre tool -1 s -1 are suggested. ' Reaction numbers have been chosen to maintain consistency with previous papers.

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