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Reactions of 1-halo-2-methyl-3-alkoxy- and 3-alkylaminopropenes with potassium tert-butoxide in tetrahydrofuran

โœ Scribed by Walsh, Raymond A.; Bottini, A. T.


Book ID
126219064
Publisher
American Chemical Society
Year
1970
Tongue
English
Weight
1006 KB
Volume
35
Category
Article
ISSN
0022-3263

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Nucleophilic substitution reactions of t
โœ A.T. Bottini; Bruce Anderson ๐Ÿ“‚ Article ๐Ÿ“… 1973 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 246 KB

In 1961, Woli.nslryl described the conversion of m-bromocamphene to a mixture of 2-and 3-tbutoxy-k,k3imethylbicyclo[3.2.l]oct-2-ene effected by potassium t-butoxide (z-BuOK), and he rationalized the reaction on the basis of a bicyclo[3.2.l]oct-2-yne intermediate (1) that adds