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Nucleophilic substitution reactions of the 2- and 3-halobicyclo[3.2.1]-Oct-2-enes with potassium t-butoxide and with sodium pyrrolidide

✍ Scribed by A.T. Bottini; Bruce Anderson

Book ID: 104238240
Publisher: Elsevier Science
Year: 1973
Tongue: French
Weight: 246 KB
Volume: 14
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)86905-7

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✦ Synopsis

In 1961, Woli.nslryl described the conversion of m-bromocamphene to a mixture of 2-and 3-tbutoxy-k,k3imethylbicyclo[3.2.l]oct-2-ene effected by potassium t-butoxide (z-BuOK), and he rationalized the reaction on the basis of a bicyclo[3.2.l]oct-2-yne intermediate (1) that adds

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