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Is the intermediate in the reaction of 3-bromo-6,7-benzobicyclo[3.2.1]octa-2,6-diene with potassium tert-butoxide an allene or an alkyne?

✍ Scribed by Taskesenligil, Yavuz; Kashyap, Ram P.; Watson, William H.; Balci, Metin


Book ID
127056221
Publisher
American Chemical Society
Year
1993
Tongue
English
Weight
387 KB
Volume
58
Category
Article
ISSN
0022-3263

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Evidence for the intermediacy of an alky
✍ Ferhan TΓΌrner; Yavuz Taşkesenligil; Metin Balci πŸ“‚ Article πŸ“… 1999 πŸ› Elsevier Science 🌐 French βš– 405 KB

In order to reveal the real intermediate in the base-promoted reaction of 1, 2-methyl derivative 16 has been synthesized and its HBr elimination reaction studied. Reaction of 16 with potassium t-butoxide did not form the corresponding allene intermediate 17 under the same reaction conditions as desc