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Reactions at high pressure, part 10: the volume profile of an intramolecular diels-alder reaction

✍ Scribed by Neil S. Isaacs; Paul Van der Beeke

Publisher
Elsevier Science
Year
1982
Tongue
French
Weight
109 KB
Volume
23
Category
Article
ISSN
0040-4039

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✦ Synopsis

the intramolecular cyclisation of furans, 3, proceeds with the following activation characteristics: J(R=Et) has EA= 72.5, H=69. 9 kJmo1 -' s" ,62Jf1 , mol-l, d= -25 cm3mol-'.

The results confirm the existence of a negative volume contribution from the approach of reagents in intermolecular analogues.

Many examples of intramolecular Diels-Alder reactions are now known 1 and are the sources of W. J. LeNoble,

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