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Organic reactions at high pressure. The Diels-Alder reaction of p-benzoquinone with dienic esters

✍ Scribed by William G. Dauben; William R. Baker

Publisher: Elsevier Science
Year: 1982
Tongue: French
Weight: 190 KB
Volume: 23
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)87410-9

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✦ Synopsis

The Diels-Alder reaction of e-benzoquinone with substituted dienoic esters affords good yields of 4a,5,8,8a-tetrahydro-1,4+aphthalenediones, free from the isomeric hydroquinone. The reactions were conducted at room temperature under 15 kbar (1.5 GPa) pressure in dichloromethane solutions.

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