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Reaction ofN-Sulfinyltrifluoromethanesulfonamide CF3SO2N=S=O with Carbonyl Compounds

✍ Scribed by B. A. Shainyan; L. L. Tolstikova

Book ID
106523518
Publisher
SP MAIK Nauka/Interperiodica
Year
2005
Tongue
English
Weight
72 KB
Volume
41
Category
Article
ISSN
1070-4280

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Homogeneous catalysis. Use of the [TiCp2
Homogeneous catalysis. Use of the [TiCp2(CF3SO3)2] catalyst for the sakurai reaction of allylic silanes with orthoesters, acetals, ketals and carbonyl compounds.
✍ T.Keith Hollis; N.P. Robinson; John Whelan; B. Bosnich πŸ“‚ Article πŸ“… 1993 πŸ› Elsevier Science 🌐 French βš– 297 KB

## The effectiveness of the [TiCp2(CF$O3)2] catalyst for the Sakurai reaction has been exploredfor a variety of allylic silanes reacting with orthoesters, ace&, ketals, aldehydes and ketones. The Sakurai reaction (eqs 1.2) is promoted by a variety of Lewis acid@ including TiQ, Alc13, BF3, MesSi R'