✦ LIBER ✦

Reactions of fluorinated acid anhydrides, (CF3CO)2O, (CF3SO2)2O and (FSO2)2O, with organometallic substrates of group 15 (As, Sb and Bi)

✍ Scribed by Debyani G. Niyogi; Sukhjinder Singh; R.D. Verma

Publisher: Elsevier Science
Year: 1995
Tongue: English
Weight: 407 KB
Volume: 70
Category: Article
ISSN: 0022-1139
DOI: 10.1016/0022-1139(94)03122-g

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Structures and conformations of trifluor

Structures and conformations of trifluoromethanesulfonic anhydride, (CF3SO2)2O, and bis(trifluoromethylsulfonyl)difluoromethane, (CF3SO2)2CF2

✍ Ralph Haist; Hans-Georg Mack; Alfred Waterfeld; Gary L. Gard; Heinz Oberhammer 📂 Article 📅 1996 🏛 Elsevier Science 🌐 English ⚖ 497 KB

Reaction of CF3 radicals with H2O and D2

Reaction of CF3 radicals with H2O and D2O

✍ Leonor Pasteris; Elena V. Oexler; Eduardo H. Staricco 📂 Article 📅 1983 🏛 John Wiley and Sons 🌐 English ⚖ 408 KB 👁 1 views

The reaction of CF3 radicals with Ha0 (D20) has been studied over the range of 533-723 K using the photolysis and the pyrolysis of CFJ as the free radical source. Arrhenius pa- rameters for the reactions where X = H or D, relative to CF:j radical recombination are given by log kHlkf'2 = (5.12 f 0.1

[2 + 3] Cycloaddition reactions of dimet

[2 + 3] Cycloaddition reactions of dimethylamino-bis(trifluoromethyl)borane, (CF3)2BNMe2, with nitrile oxides, nitrones and Me2CSO2. Crystal and molecular structure of (CF3)2B-NMe2-tBuCNO and (CF3)2BNMe2CMe2(O)O

✍ David J. Brauer; Hans Bürger; Gottfried Pawelke; Jürgen Rothe 📂 Article 📅 1996 🏛 Elsevier Science 🌐 English ⚖ 814 KB

Absolute rate constants for the self rea

Absolute rate constants for the self reactions of HO2, CF3CFHO2, and CF3O2 radicals and the cross reactions of HO2 with FO2, HO2 with CF3CFHO2, and HO2 with CF3O2 at 295 K

✍ Jens Sehested; Trine Møgelberg; Kjell Fagerström; Gharib Mahmoud; Timothy J. Wal 📂 Article 📅 1997 🏛 John Wiley and Sons 🌐 English ⚖ 175 KB 👁 2 views

The kinetics of the self-reactions of HO 2 , CF 3 CFHO 2 , and CF 3 O 2 radicals and the cross reactions of HO 2 with FO 2 , HO 2 with CF 3 CFHO 2 , and HO 2 with CF 3 O 2 radicals, were studied by pulse radiolysis combined with time resolved UV absorption spectroscopy at 295 K. The rate constants f

Atmospheric chemistry of CF3C(O)O2 radic

Atmospheric chemistry of CF3C(O)O2 radicals. Kinetics of their reaction with NO2 and kinetics of the thermal decomposition of the product CF3C(O)O2NO2

✍ Timothy J. Wallington; Jens Sehested; Ole J. Nielsen 📂 Article 📅 1994 🏛 Elsevier Science 🌐 English ⚖ 614 KB

A pulse radiolysis technique has been used to measure a rate constant of (6.6f 1.3) x lo-r2 cm3 molecule-' s-i for the association reaction between CF3C(0)02 radicals and NO2 at 295 K and one atmosphere total pressure of SF, diluent. A FAIR/ smog chamber system was used to study the thermal decompos

[2+4] and [2+2] Cycloaddition Reactions

[2+4] and [2+2] Cycloaddition Reactions of N-Sulfinyl Carboxylic Acid Amides with (CF3)2BNMe2. Crystal Structure of cyclo-(CF3)2B-NMe2-S(=O)-N=C(p-CH3C6H4)-O

✍ David J. Brauer; Hans Bürger; Gottfried Pawelke; Jürgen Rothe 📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 German ⚖ 86 KB 👁 1 views

N-sulfinylacylamides R-C(ϭO)-NϭSϭO react with (CF 3 ) 2 BNMe 2 (1) to form, by [2ϩ4] cycloaddition, six-membered rings cyclo-(CF 3 ) 2 B-NMe 2 -S(ϭO)-NϭC(R)-O for R ϭ Me (2), t-Bu (3), C 6 H 5 (4), and p-CH 3 C 6 H 4 (5) while N-sulfinylcarbamic acid esters R-O-C(ϭO)-NϭSϭO react with 1 to yield mixt