Reaction of N-Sulfinyltrifluoromethanesulfonamide CF3SO2N=S=O with Carbonyl Compounds.
β Scribed by B. A. Shainyan; L. L. Tolstikova
- Publisher
- John Wiley and Sons
- Year
- 2006
- Weight
- 16 KB
- Volume
- 37
- Category
- Article
- ISSN
- 0931-7597
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π SIMILAR VOLUMES
The barium perfluoroalkanedisulfonates Ba(O 3 S) 2 (CF 2 ) n (n = 1, 3Β±5) and the new potassium fluoroalkanedisulfonates K 2 (O 3 S) 2 CHF, K 2 (O 3 S) 2 CF 2 , and K 2 (O 3 S) 2 (CF 2 ) 5 have been prepared by reaction of (CF 2 ) n (SO 2 F) 2 (n = 1, 3Β±5) or CHF(SO 2 F) 2 with CaO (or Ca(OH) 2 ) an
N-sulfinylacylamides R-C(ΟO)-NΟSΟO react with (CF 3 ) 2 BNMe 2 (1) to form, by [2Ο©4] cycloaddition, six-membered rings cyclo-(CF 3 ) 2 B-NMe 2 -S(ΟO)-NΟC(R)-O for R Ο Me (2), t-Bu (3), C 6 H 5 (4), and p-CH 3 C 6 H 4 (5) while N-sulfinylcarbamic acid esters R-O-C(ΟO)-NΟSΟO react with 1 to yield mixt