Reaction of t-butoxy radicals with norbornadiene
β Scribed by W.Ken Busfield; Ian D. Jenkins; San H. Thang; Ezio Rizzardo; David H. Solomon
- Publisher
- Elsevier Science
- Year
- 1985
- Tongue
- French
- Weight
- 208 KB
- Volume
- 26
- Category
- Article
- ISSN
- 0040-4039
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π SIMILAR VOLUMES
The hydrogen abstraction reactions of tert-butoxyl radicals with germane, phosphine, and trimethylsilane were studied by pyrolyzing di-t-butyl peroxide in the temperature range of 403 to 458 K. From the reported rate constant for the tert-butoxy radical decomposition in the literature, the absolute
Hexafluoro-t -butoxy radicals have been generated by reacting fluorine with hexafluoro-2-methyl isopropanol: Over the temperature range of 406-600 K the hexafluoro-t-butoxy radical decomposes exclusively by loss of a CF3 radical [reaction (-2)] rather than by loss of a CH3 radical [reaction (-111:
The recent paper of Choo and Benson [l] prompted us to communicate our most recent results for the gas-phase decomposition of the t-butoxy radical. The method we have used was to decompose ditertiary butyl peroxide (-10-5M) in the presence of nitric oxide (-10-5M) and inert gas (25-1500 torr) in a s