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Reaction of para-Hydroxy-Substituted Diphenylmethanes with tert-Butoxy Radical

✍ Scribed by Catarina F. Correia; Rui M. Borges dos Santos; Sílvia G. Estácio; João P. Telo; Benedito J. Costa Cabral; José A. Martinho Simões


Publisher
John Wiley and Sons
Year
2004
Tongue
English
Weight
105 KB
Volume
5
Category
Article
ISSN
1439-4235

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Nucleophilic character of the tert-butyl
✍ H. R. Dütsch; H. Fischer 📂 Article 📅 1982 🏛 John Wiley and Sons 🌐 English ⚖ 254 KB 👁 1 views

## Abstract The decay of photochemically generated __tert__‐butyl radicals is studied at 48°C in 11 __m__‐ and __p__‐substituted toluenes by time‐resolved electron spin resonance spectroscopy. It is governed by the second‐order self‐termination perturbed by a pseudo‐first‐order reaction of the radi