## Abstract Alkyl sulfoxides were synthesized in good yields from the reaction of alkanesulfinyl chloride with Grignard reagents in the presence of zinc chloride.
Reaction of sulfoxides with grignard reagents
โ Scribed by N. A. Nesmeyanov; V. A. Kalyavin; O. A. Reutov
- Book ID
- 112441998
- Publisher
- Springer
- Year
- 1978
- Tongue
- English
- Weight
- 261 KB
- Volume
- 27
- Category
- Article
- ISSN
- 1573-9171
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๐ SIMILAR VOLUMES
3-,4-Pyridyl and 4-quinolyl Grignard reagents were generated by the reaction of the corresponding phenyl sulfoxides with PhMgBr and give the adducts upon treatment with various aldehydes and ketones. The stereochemistry for the reaction
Pyridyl Grignard reagents were prepared from the corresponding iodopyridine and EtMgBr. New cross coupling reactions of the Grignard reagents with azaheterocycles took place on the sulfinyl sulfur atom to afford biazaheteroaryls.
The reaction of 2,5-dihydrothiophene-l,l-dioxides (sulfolenes) with Grignard reagents has been studied by Krug', who could isolate halomagnesium sulfinate salts when using one mole of the