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The role of fully substituted organomagnesium compounds in the reaction of aliphatic sulfoxides with grignard reagents

โœ Scribed by N. A. Nesmeyanov; V. A. Kalyavin; O. A. Reutov


Book ID
112447453
Publisher
Springer
Year
1983
Tongue
English
Weight
440 KB
Volume
32
Category
Article
ISSN
1573-9171

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The role of impurities in the reactions
โœ Richard B. Allen; Ronald G. Lawler; Harold R. Ward ๐Ÿ“‚ Article ๐Ÿ“… 1973 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 193 KB

It has been established by chemical (2a) and CIDNP (3,4) techniques that some transition metal salts catalyze the reaction of Grignard reagents with alkyl halides by a mechanism involving free radicals. Such catalysis is probably responsible for the Wurtz coupling side reaction which lowers the yiel