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The role of impurities in the reactions of grignard reagents with alkyl bromides

✍ Scribed by Richard B. Allen; Ronald G. Lawler; Harold R. Ward

Publisher
Elsevier Science
Year
1973
Tongue
French
Weight
193 KB
Volume
14
Category
Article
ISSN
0040-4039

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✦ Synopsis

It has been established by chemical (2a) and CIDNP (3,4) techniques that some transition metal salts catalyze the reaction of Grignard reagents with alkyl halides by a mechanism involving free radicals. Such catalysis is probably responsible for the Wurtz coupling side reaction which lowers the yield of Grignard reagent obtained when magnesium of low purity is used (2b). We present further evidence here, however, that metal impurities are catalytically

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