The title reaction afforded selenophilic, carbophilic, and reduction products depending on the kinds of the organometallic reagents and the heterophilic nature of the reaction was more conspicuous in the reaction with the selenoketone than with the corresponding thioketone.
1,3- and 1,4-dienylic sulfoxides by reaction of sulfolenes and bicyclic sulfones with Grignard reagents
β Scribed by Yehiel Gaoni
- Publisher
- Elsevier Science
- Year
- 1977
- Tongue
- French
- Weight
- 180 KB
- Volume
- 18
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
β¦ Synopsis
The reaction of 2,5-dihydrothiophene-l,l-dioxides (sulfolenes) with Grignard reagents has been studied by Krug', who could isolate halomagnesium sulfinate salts when using one mole of the
π SIMILAR VOLUMES
The stereoelectronically controlled reaction of P-methoxy-1,3-dioxane (1) with Grignard reagents does not follow the course suggested by the behavior of anancomeric models for the conformational isomers of 1. Treatment of 1 with RMgX leads to the predominant formation of acid labile 3-(l'-methoxyalk
## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a βFull Textβ option. The original article is trackable v