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Reaction of sulfonyl chlorides and chlorophosphates with 1,3,2-diheterophospholanes

โœ Scribed by M. A. Pudovik; I. L. Ostanina; A. N. Pudovik


Book ID
112445358
Publisher
Springer
Year
1983
Tongue
English
Weight
310 KB
Volume
32
Category
Article
ISSN
1573-9171

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This communication reports a simple, rapid and convenient means of converting sulfonyl chlorides I to thiolsulfonate esters II using a 1:l mixture of iron pentacarbonyl and boron trifluoride ether-ate in N,N-dimethylacetamide (DMAC) or tetramethylurea (TMU). A typical procedure follows. BFx.(C7H5)7