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THE REACTION OF TRIARYL PHOSPHITES WITH SULFONYL CHLORIDES

โœ Scribed by Foshkus, A. C.; Herweh, J. E.


Book ID
126918237
Publisher
American Chemical Society
Year
1957
Tongue
English
Weight
139 KB
Volume
79
Category
Article
ISSN
0002-7863

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Reaction of iron pentacarbonyl with sulf
โœ Howard Alper ๐Ÿ“‚ Article ๐Ÿ“… 1969 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 166 KB

This communication reports a simple, rapid and convenient means of converting sulfonyl chlorides I to thiolsulfonate esters II using a 1:l mixture of iron pentacarbonyl and boron trifluoride ether-ate in N,N-dimethylacetamide (DMAC) or tetramethylurea (TMU). A typical procedure follows. BFx.(C7H5)7