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Reaction of secondary phosphines with sulfonyl chlorides

โœ Scribed by R. G. Kostyanovskii; Yu. I. El'natanov; S. V. Bondarenko


Book ID
112488483
Publisher
Springer
Year
1975
Tongue
English
Weight
185 KB
Volume
24
Category
Article
ISSN
1573-9171

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This communication reports a simple, rapid and convenient means of converting sulfonyl chlorides I to thiolsulfonate esters II using a 1:l mixture of iron pentacarbonyl and boron trifluoride ether-ate in N,N-dimethylacetamide (DMAC) or tetramethylurea (TMU). A typical procedure follows. BFx.(C7H5)7