Reaction of iron pentacarbonyl with sulf
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Howard Alper
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Article
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1969
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Elsevier Science
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French
โ 166 KB
This communication reports a simple, rapid and convenient means of converting sulfonyl chlorides I to thiolsulfonate esters II using a 1:l mixture of iron pentacarbonyl and boron trifluoride ether-ate in N,N-dimethylacetamide (DMAC) or tetramethylurea (TMU). A typical procedure follows. BFx.(C7H5)7