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Reaction of OH with HO 2 NO 2 (Peroxynitric Acid): Rate Coefficients between 218 and 335 K and Product Yields at 298 K

✍ Scribed by Jiménez, Elena; Gierczak, Tomasz; Stark, Harald; Burkholder, James B.; Ravishankara, A. R.

Book ID
126417073
Publisher
American Chemical Society
Year
2004
Tongue
English
Weight
165 KB
Volume
108
Category
Article
ISSN
1089-5639

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Rcccivcd 30 Apnl 1982 SO:, photodissociation at 193 nm (AIF cxclmer lmr) ha been used to create SO radicals; the chcmdumincsccncc from the SO + 03 reaction has been used to follow the SO ndical decay. Rate coefticicnls at 298 K of (1 07 t 0.16) x 10-r6, (1 06 f 0 16) x 10-r3, and (1 48 k 0 20) x IO-

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CS radicals have been produced by photodissociation of CS2 at 193 MI and their disappearance monitored by LIF\_ The vibrationally excited CS radicals rapidly relax to CS(v = 0). At 298 K, the rate coeffkients for CS(u = 0) reactions with 02, 03 and NO\* are (2.9 +\_ 0.4) x lo-", (3.0 + 0.4) X lo-I6

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## Abstract Azulene, which is isomeric with naphthalene, was studied to determine whether it behaves like a polycyclic aromatic hydrocarbon or an alkene in its gas‐phase reactions with OH and NO~3~ radicals and O~3~. Using relative rate methods, rate constants for the reactions of azulene with OH a